Do not substitute the bleached cake flour for all-purpose flour or unbleached flour. The high pH and starch content of unbleached cake flour will cause these cakes to collapse as well as the high protein content of all-purpose flour.
Club soda, seltzer water, and sparkling water can all be used. Do not use mineral water or tonic water as it contains variable sodium.
This batter cannot be made in advance.
Most marshmallow mishaps are temperature-related. The filling will be thick and rubbery if cooked to above 250°F, soft and runny if not cooled to 212°F, or impossibly thick if the syrup drops below 205°F as it cooks. Avoid these problems with an accurate thermometer.
Do not walk away from your thermometer while waiting for it to cool to 212°F.
When beating the marshmallow mixture when it is 212°F, it’s best to use a hand mixer, which is better able to whip the small quantity of syrup. If using a stand mixer, double the recipe.